Structural consequences of the use of hard and soft tripodal ligands during metathesis reactions: Synthesis of the [bis(hydrotris(methimazolyl)borato]bismuth(III) [bis(hydrotris(pyrazolyl)borato]sodiate

Reglinski, J. and Spicer, M.D. and Garner, M. and Kennedy, A.R. (1999) Structural consequences of the use of hard and soft tripodal ligands during metathesis reactions: Synthesis of the [bis(hydrotris(methimazolyl)borato]bismuth(III) [bis(hydrotris(pyrazolyl)borato]sodiate. Journal of the American Chemical Society, 121 (10). pp. 2317-2318. ISSN 1520-5126 (http://dx.doi.org/10.1021/ja983637f)

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Abstract

Tripodal ligands such as the hydrotris(pyrazolyl)borate anion (Tp) have found great favor in studies of structure and reactivity1 relevant to catalysis2 and inorganic biochemistry.3 Considering the accepted synthetic utility of Tp-based ligand systems, it is surprising that the range of analogous soft tripodal ligands is so limited.4 By replacing pyrazole with methimazole (2-mercapto-1-methylimidazole) in the synthetic method of Trofimenko5 (Scheme 1) we were recently successful6 in the direct synthesis of the simple tridentate, sulfur-based ligand, hydrotris(methimazolyl)borate (Tm).

ORCID iDs

Reglinski, J. ORCID logoORCID: https://orcid.org/0000-0002-0263-4168, Spicer, M.D. ORCID logoORCID: https://orcid.org/0000-0002-6000-5677, Garner, M. and Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015;
  • Item type:Article
    ID code:1286
    Dates:
    Date
    Event
    2 March 1999
    Published
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user:Users 45 not found.
    Date deposited:26 Jun 2006
    Last modified:11 Nov 2024 08:14
    URI:https://strathprints.strath.ac.uk/id/eprint/1286
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