Diazadithiafulvalenes as electron donor reagents

Koizumi, T. and Bashir, N. and Kennedy, A.R. and Murphy, J.A. (1999) Diazadithiafulvalenes as electron donor reagents. Journal of the Chemical Society, Perkin Transactions 1, 1999 (24). pp. 3637-3643. ISSN 1472-7781

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Abstract

Diazadithiafulvalenes act as excellent electron donors to arenediazonium salts. The diazadithiafulvalenium radical cations trap primary carbon radicals successfully. However, the diazadithiafulvalenium salts which form, undergo rapid ring fragmentation in contrast to their tetrathia counterparts.