Synthesis of the mixed lithium-magnesium, mixed amide (R,R/S,S)-[{LiMg(TMP)[CH2Si(Me)(2)N(SiMe3)]}(2)]: a conformationally-locked structure of five fused rings inducing two stereogenic nitrogen centres

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Kennedy, A.R. and MacLellan, J.G. and Moir, J.H. and Mulvey, R.E. and Rodger, P.J.A. (2000) Synthesis of the mixed lithium-magnesium, mixed amide (R,R/S,S)-[{LiMg(TMP)[CH2Si(Me)(2)N(SiMe3)]}(2)]: a conformationally-locked structure of five fused rings inducing two stereogenic nitrogen centres. Chemical Communications (London), 2000 (18). pp. 1757-1758. ISSN 0009-241X (http://dx.doi.org/10.1039/b004317f)

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Abstract

Reaction of the magnesium amide Mg(TMP)2 with the lithium amide LiHMDS is accompanied by an unexpected, sterically-promoted hydrogen transfer/amine elimination process, to yield the novel title compound which is the first such heterometallic composition to contain a heteroleptic amide ligand set.

ORCID iDs

Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, MacLellan, J.G., Moir, J.H., Mulvey, R.E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564 and Rodger, P.J.A.;
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