1,4-pentadienyl-3-sulfonamides: Frameworks for disfavored radical cascade cyclizations

Bommezijn, Sacha and Martin, Concepcion Gonzalez and Kennedy, Alan R. and Lizos, Dimitrios and Murphy, John A. (2001) 1,4-pentadienyl-3-sulfonamides: Frameworks for disfavored radical cascade cyclizations. Organic Letters, 3 (21). pp. 3405-3407. ISSN 1523-7060 (http://dx.doi.org/10.1021/ol0166449)

Abstract

1,4-Pentadienyl-3-sulfonamides afford products including those resulting from disfavored 5-endo-trig reactions when subjected to radical cyclization conditions. Products resulting from pathways featuring 4-exo-trig cyclizations are also detected, even when the 4-exo-trig reaction leads to a highly strained bicyclo[3.2.0] ring system.

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• Item metadata

  Item type:	Article
  ID code:	1176
  Dates:	Date Event 21 September 2001 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Users 45 not found.
  Date deposited:	26 May 2006
  Last modified:	08 Apr 2024 15:21
  URI:	https://strathprints.strath.ac.uk/id/eprint/1176