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Towards energetically viable asymmetric deprotonations : selectivity at more elevated temperatures with C2-symmetric magnesium bisamides

Bennie, Linsey Sarah and Kerr, William and Middleditch, Michael and Watson, Allan (2011) Towards energetically viable asymmetric deprotonations : selectivity at more elevated temperatures with C2-symmetric magnesium bisamides. Chemical Communications (London), 47 (8). pp. 2264-2266. ISSN 0009-241X

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    Abstract

    A novel chiral magnesium bisamide has enabled the development of effective asymmetric deprotonation protocols at substantially more elevated temperatures. This new, structurally simple, C2-symmetric magnesium complex displays excellent levels of asymmetric efficiency and energy reduction in the synthesis of enantioenriched enol silanes

    Item type: Article
    ID code: 29177
    Keywords: chemical communication, chemistry, chiral magnesium bisamide , Chemistry, Chemistry(all)
    Subjects: Science > Chemistry
    Department: Faculty of Science > Pure and Applied Chemistry
    Related URLs:
      Depositing user: Pure Administrator
      Date Deposited: 07 Mar 2011 23:27
      Last modified: 28 Mar 2014 21:11
      URI: http://strathprints.strath.ac.uk/id/eprint/29177

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