Hevia, E and Perez, J and Riera, L and Riera, V and Miguel, D (2002) Reactive alkoxide complexes of groups 6 and 7 metals. Organometallics, 21 (9). pp. 1750-1752. ISSN 0276-7333
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1021/om010977s
Abstract
Easily available alkoxo complexes [M(OR)(CO)(3)(bipy)] (M = Mn, Re) and [Mo(OR)(eta(3)-C3H5)(CO)(2)(phen)] react with dimethylacetylenedicarboxylate (DALA-D) to afford the Z-alkenyls resulting from DMAD insertion into the M-OR bonds. Evidence suggesting a nondissociative mechanism is presented.
| Item type: | Article |
|---|---|
| ID code: | 34755 |
| Keywords: | x-ray structure, carbon dioxide , oxygen bonds, carbanions, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 21 Oct 2011 13:08 |
| Last modified: | 12 Mar 2012 11:37 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/34755 |
Actions (login required)
| View Item |