Strathprints logo
Strathprints Home | Open Access | Browse | Search | User area | Copyright | Help | Library Home | SUPrimo

Reactive alkoxide complexes of groups 6 and 7 metals

Hevia, E and Perez, J and Riera, L and Riera, V and Miguel, D (2002) Reactive alkoxide complexes of groups 6 and 7 metals. Organometallics, 21 (9). pp. 1750-1752. ISSN 0276-7333

Full text not available in this repository. (Request a copy from the Strathclyde author)

Abstract

Easily available alkoxo complexes [M(OR)(CO)(3)(bipy)] (M = Mn, Re) and [Mo(OR)(eta(3)-C3H5)(CO)(2)(phen)] react with dimethylacetylenedicarboxylate (DALA-D) to afford the Z-alkenyls resulting from DMAD insertion into the M-OR bonds. Evidence suggesting a nondissociative mechanism is presented.

Item type: Article
ID code: 34755
Keywords: x-ray structure, carbon dioxide , oxygen bonds, carbanions, Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
    Depositing user: Pure Administrator
    Date Deposited: 21 Oct 2011 13:08
    Last modified: 05 Sep 2014 12:19
    URI: http://strathprints.strath.ac.uk/id/eprint/34755

    Actions (login required)

    View Item