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Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex

Allen, D.W. and Berridge, R. and Bricklebank, N. and Forder, S.D. and Palacio, F. and Coles, S.J. and Hursthouse, M.B. and Skabara, P.J. (2003) Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex. Inorganic Chemistry, 42 (13). pp. 3975-3977. ISSN 0020-1669

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Abstract

The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented 'double' charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.

Item type: Article
ID code: 830
Keywords: paramagnetic resonance, electronic-strucutre, adducts, triiodide, chains, Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
Depositing user: Mr Derek Boyle
Date Deposited: 20 Apr 2006
Last modified: 04 Sep 2014 11:57
URI: http://strathprints.strath.ac.uk/id/eprint/830

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