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Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions

Andrikopoulos, P.C. and Armstrong, D.R. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. (2005) Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions. Chemical Communications (London), 2005 (9). pp. 1131-1133. ISSN 0009-241X

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Abstract

Toluene is metallated by DABCO-activated disodium tetrabutylmagnesiate, but not by DABCO-activated monosodium tributylmagnesiate; this distinction is rationalised by DFT calculations on model systems, and the crystal structure of the main non-metallated product, which shows interstitial MgBu42- dianions within a polycationic network, is reported.

Item type: Article
ID code: 646
Keywords: magnesium, chemistry, Chemistry, Chemistry(all)
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Professional Services > Learning Services
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Depositing user: Mr Derek Boyle
Date Deposited: 28 Mar 2006
Last modified: 04 Sep 2014 12:55
URI: http://strathprints.strath.ac.uk/id/eprint/646

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