Andrikopoulos, P.C. and Armstrong, D.R. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. (2005) Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions. Chemical Communications (London), 2005 (9). pp. 1131-1133. ISSN 0009-241X
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/b416636a
Abstract
Toluene is metallated by DABCO-activated disodium tetrabutylmagnesiate, but not by DABCO-activated monosodium tributylmagnesiate; this distinction is rationalised by DFT calculations on model systems, and the crystal structure of the main non-metallated product, which shows interstitial MgBu42- dianions within a polycationic network, is reported.
| Item type: | Article |
|---|---|
| ID code: | 646 |
| Keywords: | magnesium, chemistry, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry Learning Services |
| Related URLs: | |
| Depositing user: | Mr Derek Boyle |
| Date Deposited: | 28 Mar 2006 |
| Last modified: | 12 Mar 2012 10:35 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/646 |
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