Picture of a sphere with binary code

Making Strathclyde research discoverable to the world...

The Strathprints institutional repository is a digital archive of University of Strathclyde research outputs. It exposes Strathclyde's world leading Open Access research to many of the world's leading resource discovery tools, and from there onto the screens of researchers around the world.

Explore Strathclyde Open Access research content

Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides

Drewette, K.J. and Henderson, K.W. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Rowlings, R.B. (2002) Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides. Chemical Communications (London), 2002 (11). pp. 1176-1177. ISSN 0009-241X

Full text not available in this repository. (Request a copy from the Strathclyde author)

Abstract

A series of composite lithium- or sodium-magnesium-alkoxide-diisopropylamides of general formula [{MMg[N(Pr-i)(2)](2)OR}(2)] (where M = Li, R = Oct(n); M = Na, R = Bu-n or Oct(n)), has been synthesised rationally by treating synergic amide mixtures with the appropriate alcohol.