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Towards the total synthesis of Agariblazeispirol C.

Paterson, Laura C. and Kerr, William J. and Sutherland, Andrew. (2010) Towards the total synthesis of Agariblazeispirol C. In: WestCHEM Postgraduate Symposium in Organic Chemistry, 2009-06-19, Glasgow.

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Efforts within our lab. have focused towards the synthesis of Agariblazeispirol C, 1, which was recently isolated from the cultured mycelia of Agaricus blazei. Our proposed pathway for gaining access to Agariblazeispirol C centers on the strategic employment of metal-mediated cyclisation chem. Specifically, an . Pauson-Khand reaction (PKR) will be used to construct the C/D ring section of the natural target, and a novel intramol. Heck reaction will establish the key all carbon quaternary center between rings B and C.

Item type: Conference or Workshop Item (Other)
ID code: 35030
Keywords: Agariblazeispirol C. , metal-mediated cyclisation , intramol , carbon quaternary center, Chemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Depositing user: Pure Administrator
Date Deposited: 24 Oct 2011 09:59
Last modified: 22 May 2015 09:54
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