Campbell, Ross and Garcia-Alvarez, Pablo and Kennedy, Alan R. and Mulvey, Robert E. (2010) Synergic transformation of an ethylenediamine to a lithium 1,3-diaza-2-zincacyclopentene via an alkyllithium/bis(alkyl)zinc mixture. Chemistry - A European Journal, 16 (33). pp. 9964-9968. ISSN 0947-6539Full text not available in this repository. (Request a copy from the Strathclyde author)
Four bonds in total, two NH and two CH bonds, have been cleaved from a neutral secondary diamine through the cooperative effects of a lithium alkyl–zinc bisalkyl coalition aided by N,N,N′,N′-tetramethylethylenediamine (TMEDA) to generate a dianionic diazaethene.
|Keywords:||amines, hydrides, lithium, metallacycles, zinc, directed ortho-metalation, mediated zincation, deprotonative matalation, functionalized aromatics, complexes, magnesium, Chemistry, Chemistry(all)|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Pure Administrator|
|Date Deposited:||20 Oct 2011 11:52|
|Last modified:||22 Mar 2017 11:40|