Campbell, Ross and Garcia-Alvarez, Pablo and Kennedy, Alan R. and Mulvey, Robert E. (2010) Synergic transformation of an ethylenediamine to a lithium 1,3-diaza-2-zincacyclopentene via an alkyllithium/bis(alkyl)zinc mixture. Chemistry - A European Journal, 16 (33). pp. 9964-9968. ISSN 0947-6539
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1002/chem.201001314
Abstract
Four bonds in total, two NH and two CH bonds, have been cleaved from a neutral secondary diamine through the cooperative effects of a lithium alkyl–zinc bisalkyl coalition aided by N,N,N′,N′-tetramethylethylenediamine (TMEDA) to generate a dianionic diazaethene.
| Item type: | Article |
|---|---|
| ID code: | 34026 |
| Keywords: | amines, hydrides, lithium, metallacycles, zinc, directed ortho-metalation, mediated zincation, deprotonative matalation, functionalized aromatics, zinc, complexes, magnesium, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 20 Oct 2011 12:52 |
| Last modified: | 12 Mar 2012 11:34 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/34026 |
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