Highly mismatched crystalline and amorphous GaN1−xAsx alloys in the whole composition range

Yu, K.M. and Novikov, S.V. and Broesler, R. and Demchenko, I.N. and Luckert, F. and Martin, R.W. and Denlinger, J.D. and Liliental-Weber, Z. and Walukiewicz, W. and Foxon, C.T. (2009) Highly mismatched crystalline and amorphous GaN1−xAsx alloys in the whole composition range. Journal of Applied Physics, 106 (10). p. 103709. ISSN 0021-8979 (http://dx.doi.org/10.1063/1.3259434)

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Abstract

Alloying is a commonly accepted method to tailor properties of semiconductor materials for specific applications. Only a limited number of semiconductor alloys can be easily synthesized in the full composition range. Such alloys are, in general, formed of component elements that are well matched in terms of ionicity, atom size, and electronegativity. In contrast there is a broad class of potential semiconductor alloys formed of component materials with distinctly different properties. In most instances these mismatched alloys are immiscible under standard growth conditions. Here we report on the properties of GaN1−xAsx, a highly mismatched, immiscible alloy system that was successfully synthesized in the whole composition range using a nonequilibrium low temperature molecular beam epitaxy technique. The alloys are amorphous in the composition range of 0.17<x<0.75 and crystalline outside this region. The amorphous films have smooth morphology, homogeneous composition, and sharp, well defined optical absorption edges. The band gap energy varies in a broad energy range from ∼ 3.4 eV in GaN to ∼ 0.8 eV at x ∼ 0.85. The reduction in the band gap can be attributed primarily to the downward movement of the conduction band for alloys with x>0.2, and to the upward movement of the valence band for alloys with x<0.2. The unique features of the band structure offer an opportunity of using GaN1−xAsx alloys for various types of solar power conversion devices.

ORCID iDs

Yu, K.M., Novikov, S.V., Broesler, R., Demchenko, I.N., Luckert, F., Martin, R.W. ORCID logoORCID: https://orcid.org/0000-0002-6119-764X, Denlinger, J.D., Liliental-Weber, Z., Walukiewicz, W. and Foxon, C.T.;
  • Item type:Article
    ID code:26799
    Dates:
    Date
    Event
    18 November 2009
    Published
    Subjects:Science > Physics
    Department:Faculty of Science > Physics
    Depositing user:Users 1261 not found.
    Date deposited:18 Aug 2010 09:47
    Last modified:11 Nov 2024 09:33
    URI:https://strathprints.strath.ac.uk/id/eprint/26799
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