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The use of compacted metal discs to measure Raman-spectra

Nimmo, J.A. and Bovill, A.J. and McConnell, A.A. and Smith, W.E. (1985) The use of compacted metal discs to measure Raman-spectra. Journal of Raman Spectroscopy, 16 (4). pp. 245-250. ISSN 0377-0486

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Abstract

Compacted discs prepared from a mixture of finely divided particles of a compound diluted in a large excess of metal powder facilitate the measurement of Raman spectra for some compounds which give poor scattering by conventional techniques. The method is most useful with coloured compounds. The advantages include simplicity, increased signal-to-noise ratio by factors of up to 1000 and decreased or altered fluorescence. The effect appears to be caused mainly by small crevices in the compacted metal surface which act as internal mirrors to produce many small multiple-reflection cells, but there is also evidence of an electronic interaction with the metal surface. Silver, aluminium and copper matrices were studied, silver being found to be the most advantageous, although aluminium under certain conditions may also be effective.

Item type: Article
ID code: 16794
Keywords: silver, surfaces, compacted metal discs, measuring Raman-spectra, Chemistry, Spectroscopy, Materials Science(all)
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Faculty of Humanities and Social Sciences (HaSS) > School of Government and Public Policy > Politics
Related URLs:
    Depositing user: Strathprints Administrator
    Date Deposited: 21 Mar 2010 14:43
    Last modified: 05 Sep 2014 00:31
    URI: http://strathprints.strath.ac.uk/id/eprint/16794

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