Picture of athlete cycling

Open Access research with a real impact on health...

The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by Strathclyde researchers, including by researchers from the Physical Activity for Health Group based within the School of Psychological Sciences & Health. Research here seeks to better understand how and why physical activity improves health, gain a better understanding of the amount, intensity, and type of physical activity needed for health benefits, and evaluate the effect of interventions to promote physical activity.

Explore open research content by Physical Activity for Health...

Stereochemical and mechanistic features of asymmetric Pauson-Khand processes

Kennedy, A.R. and Kerr, W.J. and Lindsay, D.M. and Scott, J.S. and Watson, S.P. (2000) Stereochemical and mechanistic features of asymmetric Pauson-Khand processes. Journal of the Chemical Society, Perkin Transactions 1, 2000 (24). pp. 4366-4372. ISSN 1472-7781

Full text not available in this repository. Request a copy from the Strathclyde author

Abstract

The absolute stereochemical configurations of a series of optically pure alkyne-Co2(CO)5PPh3 complexes and their corresponding cyclopentenones, derived from Pauson-Khand reaction with norbornene, have been established; an X-ray crystal structure of an optically pure cyclopentenone has facilitated this study. In turn, this has led to the unambiguous determination of the site of decarbonylation and alkene complexation when such monophosphine complexes are utilised in asymmetric Pauson-Khand processes.