Henderson, K.W. and Kennedy, A.R. and MacDonald, L. and McDougall, D.J. (2003) Rational design of molecular sheets composed of interconnecting eight and twenty-four membered rings: use of lithiated aggregates to control network assembly. Inorganic chemistry, 42 (9). pp. 2839-2841. ISSN 0020-1669
Full text not available in this repository. (Request a copy from the Strathclyde author)Abstract
The lithiated (organo)sulfonylacetonitrile complex [MeSO2CHCNLi·THF] (3) has been prepared and structurally characterized in order to demonstrate that well-known molecular aggregates of s-block metals may be used as building blocks in the controlled assembly of complex supramolecular architectures. The solid state structure of 3 can be described as a novel basket-weaved, 2-D network, composed of (SO2Li)2 'dimeric' rings joined via 'interdimer' donation of nitrile units.
| Item type: | Article |
|---|---|
| ID code: | 1018 |
| Keywords: | lithiated (organo)sulfonylacetonitrile complex, molecular aggregates, building blocks, supramolecular, dimeric, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry Professional Services > Information Services Directorate |
| Related URLs: | |
| Depositing user: | Catriona Mccallum |
| Date Deposited: | 15 May 2006 |
| Last modified: | 12 Mar 2012 10:36 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/1018 |
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