Ethyl 2-amino-4-isopropyl-1,3-thiazole-5-carboxylate
Kennedy, A.R. and Khalaf, A.I. and Suckling, C.J. and Waigh, R.D. (2004) Ethyl 2-amino-4-isopropyl-1,3-thiazole-5-carboxylate. Acta Crystallographica Section E: Structure Reports, 60 (8). pp. 1188-1190. ISSN 1600-5368
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Abstract
In the crystal structure of the title compound, [Mg(C4H8O)2(C9H7)2], the two indenyl ligands are bound to the Mg atom in a manner intermediate between η1- and η3-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)2 adduct (THF is tetrahydrofuran). A crystallographic C2 axis bisects the O-Mg-O angle.
| Creators(s): |
Kennedy, A.R.  ORCID: https://orcid.org/0000-0003-3652-6015, Khalaf, A.I. ORCID: https://orcid.org/0000-0001-9162-7527, Suckling, C.J. and Waigh, R.D.;
| Item type: | Article |
|---|---|
| ID code: | 958 |
| Keywords: | crystal structure, Mg atom, ring-sharing C atoms, crystallographic, Chemistry, Materials Science(all), Chemistry(all), Condensed Matter Physics |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry Faculty of Science > Strathclyde Institute of Pharmacy and Biomedical Sciences |
| Depositing user: | Catriona Mccallum |
| Date deposited: | 08 May 2006 |
| Last modified: | 13 Jul 2020 18:10 |
| URI: | https://strathprints.strath.ac.uk/id/eprint/958 |
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