Ethyl 2-amino-4-isopropyl-1,3-thiazole-5-carboxylate

Kennedy, A.R. and Khalaf, A.I. and Suckling, C.J. and Waigh, R.D. (2004) Ethyl 2-amino-4-isopropyl-1,3-thiazole-5-carboxylate. Acta Crystallographica Section E: Structure Reports, 60 (8). pp. 1188-1190. ISSN 1600-5368

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Abstract

In the crystal structure of the title compound, [Mg(C4H8O)2(C9H7)2], the two indenyl ligands are bound to the Mg atom in a manner intermediate between η1- and η3-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)2 adduct (THF is tetra­hydro­furan). A crystallographic C2 axis bisects the O-Mg-O angle.

Author(s):Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Khalaf, A.I. ORCID logoORCID: https://orcid.org/0000-0001-9162-7527, Suckling, C.J. and Waigh, R.D.
Item type:Article
ID code:958
Keywords:crystal structure, Mg atom, ring-sharing C atoms, crystallographic, Chemistry, Materials Science(all), Chemistry(all), Condensed Matter Physics
Subjects:Science > Chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Faculty of Science > Strathclyde Institute of Pharmacy and Biomedical Sciences
Depositing user: Catriona Mccallum
Date deposited:08 May 2006
Last modified:03 Jan 2020 05:58
URI:https://strathprints.strath.ac.uk/id/eprint/958
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