A palladium inverse crown : synthesis and characterisation

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Krämer, Felix and Kennedy, Alan R. and Fernández, Israel and Mulvey, Robert E. (2025) A palladium inverse crown : synthesis and characterisation. Chemical Communications, 62 (4). pp. 1215-1219. ISSN 1364-548X (https://doi.org/10.1039/D5CC06236E)

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Abstract

A unique palladium inverse crown complex in [Cs2(18-crown-6)2]2+ [(PdPtBuPh)6(PPh)]2− is presented where a neutral (PdP)6 ring hosts the dianionic PhP2− guest. Characterised by SC-XRD and high-resolution mass spectrometry, its solution constitution in THF is probed by DOSY and multinuclear NMR with quantitative insight into its bonding by DFT calculations.

ORCID iDs

Krämer, Felix, Kennedy, Alan R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Fernández, Israel and Mulvey, Robert E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564;
  • Item type:Article
    ID code:94946
    Dates:
    Date
    Event
    9 December 2025
    Published
    9 December 2025
    Published Online
    9 December 2025
    Accepted
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:09 Dec 2025 15:58
    Last modified:26 Jan 2026 08:50
    URI:https://strathprints.strath.ac.uk/id/eprint/94946
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