New insights into gas-driven phase segregation in andesitic enclaves from Mt. Mazama (Crater Lake), USA

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Oppenheimer, Julie and Cashman, Katharine V. and Rust, Alison C. and Bacon, Charles R. and Lindoo, Amanda and Dobson, Katherine J. (2025) New insights into gas-driven phase segregation in andesitic enclaves from Mt. Mazama (Crater Lake), USA. Bulletin of Volcanology, 87. 65. ISSN 1432-0819 (https://doi.org/10.1007/s00445-025-01855-8)

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Abstract

A key process in active magmatic systems is the “recharge” of deep-sourced mafic magma into cooler, more evolved, and crystal-rich shallow reservoirs; recharge may be the cause of, or response to, eruptive activity. Although compositional evidence for recharge has been extensively documented, physical models of recharge are limited, particularly processes that separate exsolving volatiles and melts from rapidly growing crystals. To improve constraints on phase separation behaviors, we re-examine andesitic enclaves in silicic andesite lava flows of Mt. Mazama (Crater Lake), USA, that provided early evidence of gas-driven filter pressing (Bacon, 1986). 2D and 3D imaging shows that enclaves have a sample-spanning crystal framework that is disrupted by melt patches, indicating that initially deformable crystal networks were subject to early phase reorganization. Small enclaves are poorly vesicular and require early gas loss. Large enclaves have porous cores with angular (diktytaxitic) voids that are well-connected in 3D and denser rinds with isolated pores. Large enclave rinds have similar bulk compositions to small enclaves but their less evolved cores require ~ 20% melt removal. In the large enclave, diktytaxitic core textures and gas fingering structures at the core–rind boundary suggest relatively slow late-stage outward gas migration. Both scaling arguments and evidence of outward gas/melt migration require a resistant rind. Rind formation is best explained by differential cooling and demonstrates the importance of thermal gradients for gas-driven filter pressing. A corollary is a limited time scale of recharge, enclave formation, and vesiculation to produce diktytaxitic textures, suggesting that recharge was (near) synchronous with eruption.

ORCID iDs

Oppenheimer, Julie, Cashman, Katharine V., Rust, Alison C., Bacon, Charles R., Lindoo, Amanda and Dobson, Katherine J. ORCID logoORCID: https://orcid.org/0000-0003-2272-626X;
CORE (COnnecting REpositories)