Ethyl 5-oxo-2,5-dihydro-4-isoxazolecarboxylate hydroxylamine salt

Kennedy, A.R. and Khalaf, A.I. and Suckling, C.J. and Waigh, R.D. (2003) Ethyl 5-oxo-2,5-dihydro-4-isoxazolecarboxylate hydroxylamine salt. Acta Crystallographica Section E: Structure Reports, 59 (9). pp. 1410-1412. ISSN 1600-5368

Abstract

The isoxazole proton is sufficiently acidic to give the title salt, hydroxylammonium 4-(ethyloxycarbonyl)-5-oxo-2,5-dihydroisoxazolide, NH3OH+.C6H6NO4-, in the presence of hydroxylamine. The deprotonation of the heterocyclic ring has a profound effect on its geometry, notably increasing the N-O distance by 0.05 A to 1.433 (2) A.

ORCID iDs

Kennedy, A.R. ORCID: https://orcid.org/0000-0003-3652-6015

Khalaf, A.I. ORCID: https://orcid.org/0000-0001-9162-7527

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  Item type:	Article
  ID code:	732
  Dates:	Date Event September 2003 Published
  Keywords:	Ethyl 5-oxo-2, isoxazoles, hydroxy­l­ammonium 4, heterocyclic ring, geometry, pure and applied chemistry, Chemistry, Materials Science(all), Chemistry(all), Condensed Matter Physics
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry Faculty of Science > Strathclyde Institute of Pharmacy and Biomedical Sciences
  Depositing user:	Allison Crawford
  Date deposited:	11 Apr 2006
  Last modified:	20 Jan 2021 16:54
  URI:	https://strathprints.strath.ac.uk/id/eprint/732