Ethyl 5-oxo-2,5-dihydro-4-isoxazolecarboxylate hydroxylamine salt

Kennedy, A.R. and Khalaf, A.I. and Suckling, C.J. and Waigh, R.D. (2003) Ethyl 5-oxo-2,5-dihydro-4-isoxazolecarboxylate hydroxylamine salt. Acta Crystallographica Section E: Structure Reports, 59 (9). pp. 1410-1412. ISSN 1600-5368

Full text not available in this repository.Request a copy from the Strathclyde author

Abstract

The isoxazole proton is sufficiently acidic to give the title salt, hydroxylammonium 4-(ethyloxycarbonyl)-5-oxo-2,5-dihydroisoxazolide, NH3OH+.C6H6NO4-, in the presence of hydroxylamine. The deprotonation of the heterocyclic ring has a profound effect on its geometry, notably increasing the N-O distance by 0.05 A to 1.433 (2) A.

Author(s):Kennedy, A.R., Khalaf, A.I., Suckling, C.J. and Waigh, R.D.
Item type:Article
ID code:732
Keywords:Ethyl 5-oxo-2, isoxazoles, hydroxy­l­ammonium 4, heterocyclic ring, geometry, pure and applied chemistry, Chemistry, Materials Science(all), Chemistry(all), Condensed Matter Physics
Subjects:Science > Chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Faculty of Science > Strathclyde Institute of Pharmacy and Biomedical Sciences
Depositing user: Allison Crawford
Date deposited:11 Apr 2006
Last modified:03 Jan 2019 11:20
URI:https://strathprints.strath.ac.uk/id/eprint/732
Export data:
CORE (COnnecting REpositories)