Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre

Collet, Alexandra and Craig, Gavin A. and Heras Ojea, María José and Bhaskaran, Lakshmi and Wilson, Claire and Hill, Stephen and Murrie, Mark (2018) Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre. Dalton Transactions, 47 (28). pp. 9237-9240. ISSN 1477-9234 (https://doi.org/10.1039/C8DT01997E)

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Abstract

We report a trinuclear mixed-valence {CoIICoIII2} complex, where the CoII centre adopts a trigonal bipyramidal geometry, leading to a large, easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.

  • Item type:Article
    ID code:69763
    Dates:
    Date
    Event
    18 June 2018
    Published
    13 June 2018
    Accepted
    Keywords:slow magnetic relaxation, magnetic anisotropy, trigonal bipyramidal geometry, Chemistry, Chemistry(all)
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:12 Sep 2019 11:08
    Last modified:25 May 2023 10:30
    URI:https://strathprints.strath.ac.uk/id/eprint/69763
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