Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre

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Collet, Alexandra and Craig, Gavin A. and Heras Ojea, María José and Bhaskaran, Lakshmi and Wilson, Claire and Hill, Stephen and Murrie, Mark (2018) Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre. Dalton Transactions, 47 (28). pp. 9237-9240. ISSN 1477-9226 (https://doi.org/10.1039/C8DT01997E)

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Abstract

We report a trinuclear mixed-valence {CoIICoIII2} complex, where the CoII centre adopts a trigonal bipyramidal geometry, leading to a large, easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.

ORCID iDs

Collet, Alexandra, Craig, Gavin A. ORCID logoORCID: https://orcid.org/0000-0003-3542-4850, Heras Ojea, María José ORCID logoORCID: https://orcid.org/0000-0002-9290-5178, Bhaskaran, Lakshmi, Wilson, Claire, Hill, Stephen and Murrie, Mark;
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