Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre
Collet, Alexandra and Craig, Gavin A. and Heras Ojea, María José and Bhaskaran, Lakshmi and Wilson, Claire and Hill, Stephen and Murrie, Mark (2018) Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre. Dalton Transactions, 47 (28). pp. 9237-9240. ISSN 1477-9234 (https://doi.org/10.1039/C8DT01997E)
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Abstract
We report a trinuclear mixed-valence {CoIICoIII2} complex, where the CoII centre adopts a trigonal bipyramidal geometry, leading to a large, easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.
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Item type: Article ID code: 69763 Dates: DateEvent18 June 2018Published13 June 2018AcceptedKeywords: slow magnetic relaxation, magnetic anisotropy, trigonal bipyramidal geometry, Chemistry, Chemistry(all) Subjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 12 Sep 2019 11:08 Last modified: 25 May 2023 10:30 URI: https://strathprints.strath.ac.uk/id/eprint/69763
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