Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre

Collet, Alexandra and Craig, Gavin A. and Heras Ojea, María José and Bhaskaran, Lakshmi and Wilson, Claire and Hill, Stephen and Murrie, Mark (2018) Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre. Dalton Transactions, 47 (28). pp. 9237-9240. ISSN 1477-9234

[img]
Preview
Text (Collet-etal-DT2018-Slow-magnetic-relaxation-[CoIICoIII2]-complex-containing-high-magnetic-anisotropy-trigonal-bipyramidal-CoII)
Collet_etal_DT2018_Slow_magnetic_relaxation_CoIICoIII2_complex_containing_high_magnetic_anisotropy_trigonal_bipyramidal_CoII.pdf
Final Published Version
License: Creative Commons Attribution 4.0 logo

Download (802kB)| Preview

    Abstract

    We report a trinuclear mixed-valence {CoIICoIII2} complex, where the CoII centre adopts a trigonal bipyramidal geometry, leading to a large, easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.