Molecular-salt hybrids; integration of ammonia borane into lithium halides

Cascallana-Matías, Irene and Breternitz, Joachim and Baker, Annabelle and Davis, Hallam and Cussen, Edmund J. and Gregory, Duncan H. (2019) Molecular-salt hybrids; integration of ammonia borane into lithium halides. Inorganic Chemistry Frontiers, 6 (3). pp. 808-812. ISSN 2052-1553

[thumbnail of Cascallana-Matias-etal-ICF-2019-integration-of-ammonia-borane-into-lithium-halides]
Preview
 Text (Cascallana-Matias-etal-ICF-2019-integration-of-ammonia-borane-into-lithium-halides)
Cascallana_Matias_etal_ICF_2019_integration_of_ammonia_borane_into_lithium_halides.pdf
Final Published Version
License: Creative Commons Attribution 3.0 logo
Download (859kB)| Preview

    Abstract

    New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH3BH3) and [LiI](NH3BH3)2 are members of a generic [LiX]m(AB)n (X = I-, BH4-; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li+-ion conductivity more than two orders of magnitude higher than either LiBH4 or LiI.

    ORCID iDs

    Cascallana-Matías, Irene, Breternitz, Joachim, Baker, Annabelle, Davis, Hallam, Cussen, Edmund J. ORCID logoORCID: https://orcid.org/0000-0002-2899-6888 and Gregory, Duncan H.;
    • Item type:Article
      ID code:69004
      Dates:
      Date
      Event
      1 March 2019
      Published
      18 February 2019
      Published Online
      16 February 2019
      Accepted
      Keywords:lithium alanates, borohydrides, LiBH4, electrochemical stability, Chemistry, Inorganic Chemistry
      Subjects:Science > Chemistry
      Department:Faculty of Science > Pure and Applied Chemistry
      Depositing user: Pure Administrator
      Date deposited:24 Jul 2019 11:56
      Last modified:25 Mar 2021 02:12
      Related URLs:
      URI:https://strathprints.strath.ac.uk/id/eprint/69004
    CORE (COnnecting REpositories)