Molecular-salt hybrids; integration of ammonia borane into lithium halides

Cascallana-Matías, Irene and Breternitz, Joachim and Baker, Annabelle and Davis, Hallam and Cussen, Edmund J. and Gregory, Duncan H. (2019) Molecular-salt hybrids; integration of ammonia borane into lithium halides. Inorganic Chemistry Frontiers, 6 (3). pp. 808-812. ISSN 2052-1553 (https://doi.org/10.1039/c9qi00099b)

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Abstract

New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH3BH3) and [LiI](NH3BH3)2 are members of a generic [LiX]m(AB)n (X = I-, BH4-; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li+-ion conductivity more than two orders of magnitude higher than either LiBH4 or LiI.

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• Item metadata

  Item type:	Article
  ID code:	69004
  Dates:	Date Event 1 March 2019 Published 18 February 2019 Published Online 16 February 2019 Accepted
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	24 Jul 2019 11:56
  Last modified:	25 Jun 2024 01:32
  Related URLs:	Scopus publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/69004