Concerted nucleophilic aromatic substitution reactions

Rohrbach, Simon and Smith, Andrew J. and Pang, Jia Hao and Poole, Darren L. and Tuttle, Tell and Chiba, Shunsuke and Murphy, John A. (2019) Concerted nucleophilic aromatic substitution reactions. Angewandte Chemie International Edition, 58 (46). pp. 16368-16388. ISSN 1433-7851 (https://doi.org/10.1002/anie.201902216)

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Abstract

Recent developments in experimental and computational chemistry have identified a rapidly growing class of nucleophilic aromatic substitutions that proceed by concerted (cS NAr) rather than classical, two-step, S NAr mechanisms. Whereas traditional S NAr reactions require substantial activation of the aromatic ring by electron-withdrawing substituents, such activating groups are not mandatory in the concerted pathways.

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• Item metadata

  Item type:	Article
  ID code:	67652
  Dates:	Date Event 11 November 2019 Published 16 April 2019 Published Online 12 April 2019 Accepted
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	30 Apr 2019 13:53
  Last modified:	18 Apr 2024 00:24
  Related URLs:	Journal or Publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/67652