A study of diketopiperazines as electron-donor initiators in transition metal-free haloarene-arene coupling

Cumine, Florimond and Zhou, Shengze and Tuttle, Tell and Murphy, John A. (2017) A study of diketopiperazines as electron-donor initiators in transition metal-free haloarene-arene coupling. Organic and Biomolecular Chemistry, 15. 3324 - 3336. ISSN 1477-0520 (https://doi.org/10.1039/C7OB00036G)

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Abstract

Several diketopiperazines have been shown to promote carbon-carbon coupling between benzene and aryl halides in the presence of potassium tert-butoxide and without the assistance of a transition metal catalyst. The structure of the diketopiperazine has an influence on its reductive potential and can help to promote the coupling of the more challenging aryl bromides with benzene.

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• Item metadata

  Item type:	Article
  ID code:	60787
  Dates:	Date Event 19 April 2017 Published 29 March 2017 Published Online 21 March 2017 Accepted
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry Technology and Innovation Centre > Bionanotechnology
  Depositing user:	Pure Administrator
  Date deposited:	26 May 2017 14:48
  Last modified:	31 Jul 2024 01:11
  URI:	https://strathprints.strath.ac.uk/id/eprint/60787