A study of diketopiperazines as electron-donor initiators in transition metal-free haloarene-arene coupling

Cumine, Florimond and Zhou, Shengze and Tuttle, Tell and Murphy, John A. (2017) A study of diketopiperazines as electron-donor initiators in transition metal-free haloarene-arene coupling. Organic and Biomolecular Chemistry, 15. 3324 - 3336. ISSN 1477-0520 (https://doi.org/10.1039/C7OB00036G)

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Abstract

Several diketopiperazines have been shown to promote carbon-carbon coupling between benzene and aryl halides in the presence of potassium tert-butoxide and without the assistance of a transition metal catalyst. The structure of the diketopiperazine has an influence on its reductive potential and can help to promote the coupling of the more challenging aryl bromides with benzene.

ORCID iDs

Cumine, Florimond ORCID logoORCID: https://orcid.org/0000-0003-0158-7387, Zhou, Shengze, Tuttle, Tell and Murphy, John A.;
  • Item type:Article
    ID code:60787
    Dates:
    Date
    Event
    19 April 2017
    Published
    29 March 2017
    Published Online
    21 March 2017
    Accepted
    Keywords:diketopiperazines, electron donors, carbon-carbon coupling, catalysts, aryl bromides, aryl halides, benzene, Chemistry, Organic Chemistry
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Technology and Innovation Centre > Bionanotechnology
    Depositing user: Pure Administrator
    Date deposited:26 May 2017 14:48
    Last modified:16 Nov 2023 01:51
    URI:https://strathprints.strath.ac.uk/id/eprint/60787
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