Tandem chemoselective Suzuki-Miyaura cross-coupling enabled by nucleophile speciation control
Seath, Ciaran P. and Fyfe, James W. B. and Molloy, John J. and Watson, Allan J. B. (2015) Tandem chemoselective Suzuki-Miyaura cross-coupling enabled by nucleophile speciation control. Angewandte Chemie, 54 (34). pp. 9976-9979. ISSN 0044-8249
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Official URL: https://doi.org/10.1002/ange.201504297
Abstract
Control of boronic acid speciation is presented as a strategy to achieve nucleophile chemoselectivity in the Suzuki-Miyaura reaction. Combined with simultaneous control of oxidative addition and transmetallation, this enables chemoselective formation of two C-C bonds in a single operation, providing a method for the rapid preparation of highly functionalized carbogenic frameworks.
Creators(s): |
Seath, Ciaran P. ![]() ![]() ![]() | Item type: | Article |
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ID code: | 53425 |
Notes: | This is the peer reviewed version of the following article: Seath, C. P., Fyfe, J. W. B., Molloy, J. J., & Watson, A. J. B. (2015). Tandem chemoselective Suzuki-Miyaura cross-coupling enabled by nucleophile speciation control. Angewandte Chemie, which has been published in final form at http://www.dx.doi.org/10.1002/ange.201504297. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving |
Keywords: | boron, chemoselectivity, cross-coupling, palladium, speciation, Chemistry, Chemistry(all) |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 18 Jun 2015 15:09 |
Last modified: | 25 Jan 2021 03:26 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/53425 |
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