Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes
Kennedy, Alan R and Kerr, William and Moir, Rory and Reid, Marc (2014) Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes. Organic and Biomolecular Chemistry, 12 (40). pp. 7927-7931. ISSN 1477-0520 (https://doi.org/10.1039/C4OB01570C)
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Abstract
Synthesis of a series of iridium(I) complexes of the type [(COD)Ir(IMes)(PPh3)]X (X = BF4, OTf, and BArF) has been established. Application of these species in mild hydrogen isotope exchange processes revealed more efficient catalysis and, further, a wider solvent scope when employing larger, more weakly coordinating counterions.
ORCID iDs
Kennedy, Alan R ORCID: https://orcid.org/0000-0003-3652-6015, Kerr, William ORCID: https://orcid.org/0000-0002-1332-785X, Moir, Rory and Reid, Marc ORCID: https://orcid.org/0000-0003-4394-3132;-
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Item type: Article ID code: 49163 Dates: DateEventOctober 2014Published2 September 2014Published Online1 September 2014AcceptedSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 10 Sep 2014 11:34 Last modified: 25 Sep 2024 00:36 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/49163
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