Insights into the decomposition of olefin metathesis precatalysts

Manzini, Simone and Poater, Albert and Nelson, David J and Cavallo, Luigi and Slawin, Alexandra M Z and Nolan, Steven P (2014) Insights into the decomposition of olefin metathesis precatalysts. Angewandte Chemie International Edition. (https://doi.org/10.1002/anie.201403770)

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Abstract

The decomposition of a series of benzylidene, methylidene, and 3-phenylindenylidene complexes has been probed in alcohol solution in the presence of base. Tricyclohexylphosphane-containing precatalysts are shown to yield [RuCl(H)(H2 )(PCy3 )2 ] in isopropyl alcohol solutions, while 3-phenylindenylidene complexes lead to η(5) -(3-phenyl)indenyl products. The potential-energy surfaces for the formation of the latter species have been probed using density functional theory studies.

ORCID iDs

Manzini, Simone, Poater, Albert, Nelson, David J ORCID logoORCID: https://orcid.org/0000-0002-9461-5182, Cavallo, Luigi, Slawin, Alexandra M Z and Nolan, Steven P;
  • Item type:Article
    ID code:48901
    Dates:
    Date
    Event
    2 June 2014
    Published
    2 June 2014
    Published Online
    Notes:© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
    Keywords:density functional calculations, hydride ligands, metathesis, reaction mechanisms, ruthenium, Physical and theoretical chemistry, Chemistry(all), Catalysis
    Subjects:Science > Chemistry > Physical and theoretical chemistry
    Department:UNSPECIFIED
    Depositing user: Pure Administrator
    Date deposited:02 Jul 2014 10:22
    Last modified:21 May 2023 03:40
    URI:https://strathprints.strath.ac.uk/id/eprint/48901
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