Insights into the decomposition of olefin metathesis precatalysts
Manzini, Simone and Poater, Albert and Nelson, David J and Cavallo, Luigi and Slawin, Alexandra M Z and Nolan, Steven P (2014) Insights into the decomposition of olefin metathesis precatalysts. Angewandte Chemie International Edition. ISSN 1521-3773 (https://doi.org/10.1002/anie.201403770)
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The decomposition of a series of benzylidene, methylidene, and 3-phenylindenylidene complexes has been probed in alcohol solution in the presence of base. Tricyclohexylphosphane-containing precatalysts are shown to yield [RuCl(H)(H2 )(PCy3 )2 ] in isopropyl alcohol solutions, while 3-phenylindenylidene complexes lead to η(5) -(3-phenyl)indenyl products. The potential-energy surfaces for the formation of the latter species have been probed using density functional theory studies.
ORCID iDs
Manzini, Simone, Poater, Albert, Nelson, David J ORCID: https://orcid.org/0000-0002-9461-5182, Cavallo, Luigi, Slawin, Alexandra M Z and Nolan, Steven P;-
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Item type: Article ID code: 48901 Dates: DateEvent2 June 2014Published2 June 2014Published OnlineNotes: © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Subjects: Science > Chemistry > Physical and theoretical chemistry Department: UNSPECIFIED Depositing user: Pure Administrator Date deposited: 02 Jul 2014 10:22 Last modified: 06 Sep 2024 12:27 URI: https://strathprints.strath.ac.uk/id/eprint/48901