Efficient C-N and C-S bond formation using the highly active [Ni(allyl)Cl(IPr*OMe)] precatalyst
Martin, Anthony R. and Nelson, David and Meiries, Sébastien and Slawin, Alexandra M.Z. and Nolan, Steven P. (2014) Efficient C-N and C-S bond formation using the highly active [Ni(allyl)Cl(IPr*OMe)] precatalyst. European Journal of Organic Chemistry. ISSN 1434-193X (https://doi.org/10.1002/ejoc.201402022)
Full text not available in this repository.Request a copyAbstract
Two new [Ni(allyl)Cl(NHC)] complexes with the bulky yet flexible N-heterocyclic carbene (NHC) ligands IPr* {N,N'-bis[2,6-bis(diphenylmethyl)-4-methylphenyl]imidazole-2-ylidene} and IPr*OMe {N,N'-bis[2,6-bis(diphenylmethyl)-4-methoxyphenyl]imidazol-2-ylidene} are reported. These complexes were employed in the amination and sulfination of aryl halide species and were shown to perform well in these reactions, which typically required less than half as much catalyst as previous state-of-the-art nickel complexes.
ORCID iDs
Martin, Anthony R., Nelson, David ORCID: https://orcid.org/0000-0002-9461-5182, Meiries, Sébastien, Slawin, Alexandra M.Z. and Nolan, Steven P.;-
-
Item type: Article ID code: 47882 Dates: DateEvent7 March 2014Published7 March 2014Published Online2014AcceptedSubjects: Science > Chemistry Department: UNSPECIFIED Depositing user: Pure Administrator Date deposited: 07 May 2014 12:53 Last modified: 13 Oct 2024 10:07 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/47882