A novel neutral organic electron donor with record half-wave potential

Farwaha, Hardeep S and Bucher, Gotz and Murphy, John A (2013) A novel neutral organic electron donor with record half-wave potential. Organic and Biomolecular Chemistry, 11. pp. 8073-8081. ISSN 1477-0520

[img]
Preview
 PDF (Farwaha-etal-OBC2013-novel-neutral-organic-electron-donor)
Farwaha_etal_OBC2013_novel_neutral_organic_electron_donor.pdf
Accepted Author Manuscript
Download (1MB)| Preview

    Abstract

    Tricyclic donor 26 has been prepared and is the most reducing neutral ground-state organic molecule known, with an oxidation potential 260 mV more negative than the previous record. Cyclic voltammetry shows that a 2-electron reversible redox process occurs in DMF as solvent at −1.46 V vs. Ag/AgCl.

    Creators(s): Farwaha, Hardeep S ORCID logoORCID: https://orcid.org/0000-0003-0570-005X, Bucher, Gotz and Murphy, John A;
    Item type:Article
    ID code:46029
    Keywords:Chemistry, Organic Chemistry
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:20 Nov 2013 15:22
    Last modified:09 Nov 2020 02:27
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/46029
    Export data:
    CORE (COnnecting REpositories)