Multivalent nanoparticle networks as ultrasensitive enzyme sensors

De La Rica, Roberto and Fratila, Raluca and Szarpak, Anna and Huskens, Jurriaan and Velders, Aldrik (2011) Multivalent nanoparticle networks as ultrasensitive enzyme sensors. Angewandte Chemie International Edition, 50 (25). 5704–5707. ISSN 1433-7851

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Abstract

As few as 23 enzyme molecules could be detected on the basis of the dispersion of Au nanoparticles in a model bioassay whose sensitivity was boosted by the interplay between multivalent and monovalent supramolecular interactions: a diferrocenyl ligand (red) caused the assembly of nanoparticle clusters; upon its oxidation, a competing monovalent guest molecule (blue) favored the formation of monovalent interactions for more efficient

Author(s):De La Rica, Roberto, Fratila, Raluca, Szarpak, Anna, Huskens, Jurriaan and Velders, Aldrik
Item type:Article
ID code:45688
Keywords:biosensors, cyclodextrins, enzymes, gold, supramolecular chemistry, Physics, Physics and Astronomy(all)
Subjects:Science > Physics
Department:Faculty of Science > Physics
Depositing user: Pure Administrator
Date deposited:06 Nov 2013 11:23
Last modified:18 Oct 2019 03:48
URI:https://strathprints.strath.ac.uk/id/eprint/45688
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