Light-responsive capture and release of DNA in a ternary supramolecular complex

Nalluri, Siva Krishna Mohan and Voskuhl, Jens and Bultema, Jelle B and Boekema, Egbert J and Ravoo, Bart Jan (2011) Light-responsive capture and release of DNA in a ternary supramolecular complex. Angewandte Chemie International Edition, 50 (41). pp. 9747-9751. ISSN 1433-7851

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Abstract

The wavelength determines whether DNA is captured in a light-responsive ternary supramolecular complex or released (see scheme). The reversible binding of DNA is triggered by a photoisomerization, which switches the complex from a multivalent to a monovalent binding mode.