Metal-free reductive cleavage of benzylic esters and ethers, fragmentations result from single and double electron transfers
Doni, Eswararao and O'Sullivan, Steven and Murphy, John A (2013) Metal-free reductive cleavage of benzylic esters and ethers, fragmentations result from single and double electron transfers. Angewandte Chemie International Edition, 52 (8). pp. 2239-2242. ISSN 1521-3773 (https://doi.org/10.1002/anie.201208066)
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The mechanisms for the reductive cleavage of benzylic esters and ethers by neutral organic electron donor 1 are different (see scheme). Products isolated from the cleavage of benzylic ethers result from the transfer of two electrons, without the intermediacy of benzyl radicals, which are believed to be intermediates in the reductive cleavage of benzylic esters.
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Item type: Article ID code: 43006 Dates: DateEvent18 February 2013Published11 January 2013Published OnlineSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 26 Feb 2013 14:47 Last modified: 11 Nov 2024 10:21 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/43006
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