Unexpectedly selective formation and reactions of epoxycyclooctenones under microwave-mediated conditions
Fawcett, John and Griffith, Gerry A and Percy, Jonathan and Uneyama, Emi (2004) Unexpectedly selective formation and reactions of epoxycyclooctenones under microwave-mediated conditions. Organic Letters, 6 (8). pp. 1277-1280. ISSN 1523-7060 (https://doi.org/10.1021/ol0496327)
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Topologically mobile difluorinated cyclooctenones undergo rapid, high-yielding, and completely stereoselective epoxidations with methyl-(trifluoromethyl)dioxirane. The epoxides resist conventional hydrolysis but react smoothly in basic media under microwave irradiation to afford unique hemiacetals and hemiaminals in good yield.
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Item type: Article ID code: 38966 Dates: DateEvent2004PublishedSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 04 Apr 2012 15:30 Last modified: 08 Apr 2024 19:53 URI: https://strathprints.strath.ac.uk/id/eprint/38966
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