Star-shaped π-conjugated oligomers and their applications in organic electronics and photonics
Kanibolotsky, Alexander L. and Perepichka, Igor F. and Skabara, Peter J. (2010) Star-shaped π-conjugated oligomers and their applications in organic electronics and photonics. Chemical Society Reviews, 39 (7). pp. 2695-2728. ISSN 0306-0012 (https://doi.org/10.1039/b918154g)
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Abstract
Abstract: Strategies for the design and construction of non-linear, 2D and 3D conjugated macromolecules are presented in this critical review. The materials, termed here as star-shaped structures, feature a core unit which may or may not provide conjugated links between arms that radiate like spokes from a central axle. The arms of the macromolecules consist of linear oligomers or irregular conjugated chains lacking a formal repeat unit. The cores range from simple atoms to single or fused aromatic units and can provide a high level of symmetry to the overall structure. The physical properties of the star-shaped materials can be markedly different to their simple, linear conjugated analogues. These differences are highlighted and we report on anomalies in absorption/emission characteristics, electronic energy levels, thermal properties and morphology of thin films. We provide numerous examples for the application of star-shaped conjugated macromolecules in organic semiconductor devices; a comparison of their device performance with those comprising analogous linear systems provides clear evidence that the star-shaped compounds are an important class of material in organic electronics. Moreover, these structures are monodisperse, well-defined, discrete molecules with 100% synthetic reproducibility, and possess high purity and excellent solubility in common organic solvents. They feature many of the attributes of plastic materials (good film-forming properties, thermal stability, flexibility) and are therefore extremely attractive alternatives to conjugated polymers.
ORCID iDs
Kanibolotsky, Alexander L. ORCID: https://orcid.org/0000-0003-3991-6297, Perepichka, Igor F. and Skabara, Peter J.;-
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Item type: Article ID code: 28455 Dates: DateEvent1 July 2010Published2 June 2010Published OnlineSubjects: Science > Chemistry > Physical and theoretical chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Mrs Roslyn MacDonald Date deposited: 13 May 2011 12:09 Last modified: 30 Nov 2024 07:06 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/28455