Super-electron donors : bis-pyridinylidene formation by base treatment of pyridinium salts
Murphy, J.A. and Garnier, J. and Park, S.R. and Schoenebeck, F. and Zhou, S.Z. and Turner, A.T. (2008) Super-electron donors : bis-pyridinylidene formation by base treatment of pyridinium salts. Organic Letters, 10 (6). pp. 1227-1230. ISSN 1523-7060
Full text not available in this repository.Request a copy from the Strathclyde authorOfficial URL: https://doi.org/10.1021/ol800134g
Abstract
Deprotonation of bispyridinium salt 7b affords bispyridinylidene 10, a very powerful neutral organic two-electron donor [E1/2 (DMF) = −1.13 V vs Ag/AgCl/KCl (sat)], presumably via the pyridinylidene 8. Donor 10 reduces aryl iodides and bromides to aryl anions in excellent yield and also reductively cleaves selected phenylalkylsulfones very efficiently.
Author(s): | Murphy, J.A., Garnier, J., Park, S.R., Schoenebeck, F., Zhou, S.Z. and Turner, A.T. | Item type: | Article |
---|---|
ID code: | 19761 |
Keywords: | super-electron donors, bis-pyridinylidene, pyridinium salts, Chemistry, Biochemistry, Organic Chemistry, Physical and Theoretical Chemistry |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Strathprints Administrator |
Date deposited: | 02 Jun 2010 17:02 |
Last modified: | 13 Dec 2019 05:29 |
URI: | https://strathprints.strath.ac.uk/id/eprint/19761 |
Export data: |
CORE (COnnecting REpositories)