Allylic fluorination via an unusual alkene z/e isomerisation
Laurenson, J.A.B. and Meiries, S. and Percy, J.M. and Roig, R., University of Leicester (Funder), Engineering and Physical Sciences Research Council (EPSRC) (Funder), WestCHEM (Funder) (2009) Allylic fluorination via an unusual alkene z/e isomerisation. Tetrahedron Letters, 50 (26). pp. 3571-3573. ISSN 0040-4039 (http://dx.doi.org/10.1016/j.tetlet.2009.03.068)
Full text not available in this repository.Request a copyAbstract
The isomerisation of readily available (Z)-4-(para-methoxybenzyloxy)- 1 -chloro-2-butene was achieved under mild conditions to afford the much less accessible E-diastereoisomer. This was an effective Substrate in Sharpless asymmetric dihydroxylation (AD) reactions, delivering highly enantiomerically enriched fluorinated butene triol building blocks.
-
-
Item type: Article ID code: 19093 Dates: DateEvent1 July 2009PublishedSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Strathprints Administrator Date deposited: 15 Jun 2010 09:26 Last modified: 16 Aug 2024 13:10 URI: https://strathprints.strath.ac.uk/id/eprint/19093