Superelectrophilic amidine dications : dealkylation by triflate anion

Kovacevic, Luka S and Idziak, Christopher and Markevicius, Augustinas and Scullion, Callum and Corr, Michael James and Kennedy, Alan and Tuttle, Tell and Murphy, John A (2012) Superelectrophilic amidine dications : dealkylation by triflate anion. Angewandte Chemie International Edition, 51 (34). pp. 8516-8519. ISSN 1433-7851 (https://doi.org/10.1002/anie.201202990)

Abstract

Superelectrophiles: Formamides were designed that when treated with triflic anhydride would be transformed into superelectrophilic amidine dications. These dications were so electrophilic that they underwent in situ dealkylation by the triflate anion (see scheme; Tf = trifluoromethanesulfonyl). DFT calculations were used to determine the mechanistic details of the dealkylation reaction.

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• Item metadata

  Item type:	Article
  ID code:	40435
  Dates:	Date Event 20 August 2012 Published 13 July 2012 Published Online
  Notes:	Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
  Subjects:	Science > Chemistry > Physical and theoretical chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry Technology and Innovation Centre > Bionanotechnology
  Depositing user:	Pure Administrator
  Date deposited:	17 Jul 2012 14:10
  Last modified:	08 Apr 2024 20:02
  Related URLs:	Journal or Publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/40435