Evidence for extreme activation of carbon-hydrogen bonds in [(PhCH2)2NNa]n : resultant carbon-hydrogen bond cleavage to give {[PhC(H)NC(H)Ph]Na.cntdot.PMDETA}n

Andrews, Philip C. and Armstrong, David R. and Mulvey, Robert and Reed, David (1988) Evidence for extreme activation of carbon-hydrogen bonds in [(PhCH2)2NNa]n : resultant carbon-hydrogen bond cleavage to give {[PhC(H)NC(H)Ph]Na.cntdot.PMDETA}n. Journal of the American Chemical Society, 110 (15). pp. 5235-5236. ISSN 0002-7863 (https://doi.org/10.1021/ja00223a076)

Abstract

In organolithium chemistry evidence is accumulating that lithium atoms situated in abnormally low coordination environments then proceed to interact with nearby CH units of the ligands. For example, the crystal structure of [(PhCH,),NLi], revealed a planar (NLi)3 ring whose formally just two-coordinate metal atoms form close contacts with CHpCoCH portions of the benzyl groups.

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• Item metadata

  Item type:	Article
  ID code:	37564
  Dates:	Date Event 20 July 1988 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	09 Feb 2012 19:23
  Last modified:	08 Apr 2024 19:49
  URI:	https://strathprints.strath.ac.uk/id/eprint/37564