Crystal structure of sodium iodide·(diglyme) : An unprecedented bridging role for diglyme

Mulvey, Robert and Clegg, W. and Barr, Donald and Snaith, R. (1986) Crystal structure of sodium iodide·(diglyme) : An unprecedented bridging role for diglyme. Polyhedron, 5 (12). pp. 2109-2111. ISSN 0277-5387 (https://doi.org/10.1016/S0277-5387(00)87147-8)

Abstract

The diglyme adduct of sodium iodide, NaI·(CH3OCH2CH2)2O, has been structurally characterized by X-ray diffraction. It forms infinite zig-zag chains which, unlike most complexes of the salt, retain NaI bonds. In addition, diglyme molecules bridge pairs of Na atoms through four-co-ordinate O atoms, so representing a new role for this neutral oxygen donor.

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• Item metadata

  Item type:	Article
  ID code:	37560
  Dates:	Date Event 1986 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	09 Feb 2012 17:52
  Last modified:	08 Apr 2024 19:48
  URI:	https://strathprints.strath.ac.uk/id/eprint/37560