The structural isomers of {[ph(2-pyridyl)NLi]·[OP(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1984) The structural isomers of {[ph(2-pyridyl)NLi]·[OP(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands. Journal of the Chemical Society, Chemical Communications (11). pp. 700-701. ISSN 0022-4936 (https://doi.org/10.1039/C39840000700)

Abstract

An X-ray crystallographic study of the title compound, (1), shows it to consist of two structural isomers, one, (1A), with a planar (LiN)2 ring structure provided by µ-amido ligands, but the other,(1B), with an (LiO)2 ring due to previously unobserved bridging by the oxygen of formally neutral ligand.

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• Item metadata

  Item type:	Article
  ID code:	37488
  Dates:	Date Event 1984 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	08 Feb 2012 15:35
  Last modified:	08 Apr 2024 19:48
  URI:	https://strathprints.strath.ac.uk/id/eprint/37488