A simple method for the α-oxygenation of aldehydes

Beshara, Cory S. and Hall, Adrian and Jenkins, Robert L. and Jones, Teyrnon C. and Parry, Rachael T. and Thomas, Stephen P. and Tomkinson, Nicholas C. O. (2005) A simple method for the α-oxygenation of aldehydes. Chemical Communications (11). pp. 1478-1480. ISSN 1359-7345 (https://doi.org/10.1039/b418101h)

Abstract

A mild, efficient and general method for the chemospecific α-oxygenation of aldehydes is described. Treatment of a series of aldehydes with N-tert-butyl-O-benzoyl hydroxylamine hydrochloride gives the corresponding α-oxygenated carbonyl via a proposed pericyclic rearrangement process.

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• Item metadata

  Item type:	Article
  ID code:	34200
  Dates:	Date Event 2005 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	20 Oct 2011 14:10
  Last modified:	08 Apr 2024 19:29
  URI:	https://strathprints.strath.ac.uk/id/eprint/34200