Vibrational spectra of EDTA complexes of divalent tin and lead

Nuttall, R.H. and McConnell, A.A. (1977) Vibrational spectra of EDTA complexes of divalent tin and lead. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 33 (3-4). pp. 459-462. ISSN 1386-1425 (http://dx.doi.org/10.1016/0584-8539(77)80056-1)

Abstract

The vibrational spectra of Na2SnEDTA·2H2O and Na2PbEDTA·2H2O in solution, and as solids, suggest that the species present in the two phases are essentially similar. The spectra can be assigned on the basis of a C2υψ-heptaco-ordinate arrangement about the metal. Comparison with the vibrational spectra of binuclear tin and lead complexes suggests that Pb2EDTA has a similar structure to that established for Sn2EDTA·2H2O, but with slight changes in bond distances.

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• Item metadata

  Item type:	Article
  ID code:	16804
  Dates:	Date Event 1977 Published
  Notes:	AHR
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Strathprints Administrator
  Date deposited:	22 Mar 2010 10:19
  Last modified:	08 Apr 2024 17:17
  URI:	https://strathprints.strath.ac.uk/id/eprint/16804