Murphy, J.A. and Khan, T.A. and Zhou, S. and Mohan, M. and Thomson, D.W. (2005) Highly efficient reduction of unactivated aryl and alkyl iodides by a ground-state neutral organic electron donor. Angewandte Chemie, 44 (9). pp. 1356-1360.Full text not available in this repository. (Request a copy from the Strathclyde author)
Electron-transfer reductions of unactivated aryl and alkyl iodides with a neutral ground-state organic molecule are reported. The reducing agent 1 is formed in two steps from N-methylbenzimidazole using very simple chemistry, and subsequent treatment of the iodoalkane or -arene with 1 affords cyclized products (see scheme).
|Keywords:||cyclization, synthetic methods, reduction, radical reactions, electron transfer, Chemistry, Medicine(all)|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry
|Depositing user:||Strathprints Administrator|
|Date Deposited:||14 Nov 2011 11:43|
|Last modified:||22 Jul 2016 02:15|