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Highly efficient reduction of unactivated aryl and alkyl iodides by a ground-state neutral organic electron donor

Murphy, J.A. and Khan, T.A. and Zhou, S. and Mohan, M. and Thomson, D.W. (2005) Highly efficient reduction of unactivated aryl and alkyl iodides by a ground-state neutral organic electron donor. Angewandte Chemie, 44 (9). pp. 1356-1360. ISSN 1521-3757

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Abstract

Electron-transfer reductions of unactivated aryl and alkyl iodides with a neutral ground-state organic molecule are reported. The reducing agent 1 is formed in two steps from N-methylbenzimidazole using very simple chemistry, and subsequent treatment of the iodoalkane or -arene with 1 affords cyclized products (see scheme).

Item type: Article
ID code: 9884
Notes: PV: 21365
Keywords: cyclization, synthetic methods, reduction, radical reactions, electron transfer, Chemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Unknown Department
Related URLs:
    Depositing user: Strathprints Administrator
    Date Deposited: 14 Nov 2011 11:43
    Last modified: 16 Jul 2013 21:47
    URI: http://strathprints.strath.ac.uk/id/eprint/9884

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