Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. and Sherrington, D.C. (2004) Synthesis, structure and methyl methacrylate polymerisation activity of a mixed pi-ferrocene pi-toluene complex of potassium tris(hexamethyldisilazide)magnesiate. Organometallics, 23 (6). pp. 1197-1199. ISSN 0276-7333
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://pubs.acs.org/cgi-bin/article.cgi/orgnd7/200...
Abstract
Treating a toluene solution of mixed potassium-magnesium tris(hexamethyldisilazide) with ferrocene yields a surprising complex exhibiting simultaneous arene and metallocene -coordination of K+, which when prepared in situ initiates the polymerization of MMA to give syndio-rich PMMA.
| Item type: | Article |
|---|---|
| ID code: | 959 |
| Keywords: | toluene, potassium-magnesium, hexamethyldisilazide, ferrocene, polymerization, PMMA, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Catriona Mccallum |
| Date Deposited: | 08 May 2006 |
| Last modified: | 12 Mar 2012 10:36 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/959 |
Actions (login required)
| View Item |