Berridge, R. and Skabara, P.J. and Andreu, R. and Garin, J. and Orduna, J. and Torra, M. (2005) Probing the conformational changes upon oxidation in cross-conjugated architectures featuring vinylogous TTF units. Tetrahedron Letters, 46 (46). pp. 7871-7875. ISSN 0040-4039
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://www.dx.doi.org/10.1016/j.tetlet.2005.09.108
Abstract
We report the synthesis and electropolymerisation of 1,3,5-tris(1,3-dithiole-2-ylidenephenylene)benzene 4. The resulting polymer features extended tetrathiafulvalene (TTF) units and can be considered as a cross-conjugated, cross-linked structure. Upon p-doping, electrochemical and UV-vis spectroelectrochemical experiments indicate that the polymer undergoes a unique coformational change within the dendralene unit from one definitive orthogonal arrangement to another.
| Item type: | Article |
|---|---|
| ID code: | 898 |
| Keywords: | dendralenes, TTF, polymers, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Mr Derek Boyle |
| Date Deposited: | 27 Apr 2006 |
| Last modified: | 12 Mar 2012 10:36 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/898 |
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