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4-Chlorobenzoic acid N, N-dimethylformamide solvate

Xu, X. and Kennedy, A.R. and Florence, A.J. and Shankland, N. (2004) 4-Chlorobenzoic acid N, N-dimethylformamide solvate. Acta Crystallographica Section E: Structure Reports, 60 (11). pp. 1950-1951. ISSN 1600-5368

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Abstract

In the title compound, C7H5ClO2.C3H7NO, the carboxyl­ic acid group of 4-chloro­benzoic acid is hydrogen bonded to a mol­ecule of N,N-di­methyl­form­amide via an R22(7) O - HO/C - HO motif. This motif takes precedence over the R22(8) O - HO dimer arrangement observed in 4-chloro­benzoic acid itself.