Khan, T. and Skabara, P.J. and Frere, P. and Allain, M. and Coles, S.J. and Hursthouse, M.B. (2004) Exceptional electron donating ability of an extended tetrathiafulvalene derivative. Tetrahedron Letters, 45 (12). pp. 2535-2539. ISSN 0040-4039Full text not available in this repository. (Request a copy from the Strathclyde author)
We report the synthesis, crystal structures and redox chemistry of two new TTF derivatives bearing fused triaryl units. Both compounds show significant planarisation within conjugated regions, assisted by close intramolecular S...O contacts. The extended-TTF analogue displays multi-redox activity and can be oxidised, sequentially to the tetracation species.
|Keywords:||tetrathiafulvalene, synthesis, X-ray crystallography, electrochemistry, Chemistry, Biochemistry, Organic Chemistry, Drug Discovery|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Mr Derek Boyle|
|Date Deposited:||21 Apr 2006|
|Last modified:||29 Apr 2016 07:40|