Khan, T. and Skabara, P.J. and Coles, S.J. and Hursthouse, M.B. (2001) A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement. Chemical Communications (London), 2001 (4). pp. 369-370. ISSN 0009-241XFull text not available in this repository. (Request a copy from the Strathclyde author)
In the presence of perchloric acid, an unusual 1,4-aryl shift is observed for two electron-rich 4,5-bis[hydroxy(aryl)methyl]-1,3-dithiole-2-thiones; the X-ray crystal structure of compound 8 confirms the structural identity of the rearrangement product.
|Keywords:||chemistry, perchloric acid, thiones, Chemistry, Chemistry(all)|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Mr Derek Boyle|
|Date Deposited:||19 Apr 2006|
|Last modified:||06 Jan 2017 03:06|