Allen, D.W. and Mifflin, J.P. and Skabara, P.J. (2000) Synthesis and solvatochromism of some dipolar aryl-phosphonium and -phosphine oxide systems. Journal of Organometallic Chemistry, 601 (2). pp. 293-298. ISSN 0022-328XFull text not available in this repository. (Request a copy from the Strathclyde author)
The synthesis is reported of a series of dipolar arylphosphonium salts bearing ferrocenylethenyl, 2-thienylethenyl, 4-dimethylaminophenylethenyl, or (4-dimethylaminophenyl)butadienyl electron-donor centres, together with a study of their course of alkaline hydrolysis, which provides a convenient synthetic route to related dipolar phosphine oxides. The phosphonium salts exhibit a modest degree of negative solvatochromism, whereas the related phosphine oxides show a small positive solvatochromic effect. In the case of the ferrocenyl systems, the electronic effects of the phosphorus acceptor group on the ferrocene unit have been studied by cyclic voltammetry.
|Keywords:||phosphonium salt, phosphine oxide, solvatochromism, ferrocenyl, cyclic voltammetry, Chemistry, Materials Chemistry, Biochemistry, Organic Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Mr Derek Boyle|
|Date Deposited:||18 Apr 2006|
|Last modified:||04 Nov 2016 03:01|