Francisco, C.G. and Gonzalez, C.C. and Kennedy, A.R. and Paz, N.R. and Suarez, E. (2006) Synthesis and stability of mixed nonfluorinated 1,1,1-trihalo-alkanes. Tetrahedron Letters, 47 (1). pp. 35-38. ISSN 0040-4039
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1016/j.tetlet.2005.10.118
Abstract
1,1,1-Trihaloalkanes of the types R-CCl2I, R-CClBrI, and R-CBr2I belonging to 1,1,1-trihalo-1-deoxy-d-arabinitol series of alditols were prepared and fully characterized by anomeric alkoxyl radical fragmentation of the corresponding 2,2-dihalo-2-deoxy-d-arabino-hexopyranose derivatives. The analogous diiodohalo compounds R-CClI2 and R-CBrI2 could not be prepared by this methodology. The results strongly suggest that the stability of the mixed trihalo alditols decreases with increasing bulkiness of the halogen atoms.
| Item type: | Article |
|---|---|
| ID code: | 728 |
| Keywords: | stability, nonfluorinated, trihalo-alkanes, Chemistry, Electrical engineering. Electronics Nuclear engineering |
| Subjects: | Science > Chemistry Technology > Electrical engineering. Electronics Nuclear engineering |
| Department: | Faculty of Engineering > Electronic and Electrical Engineering Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Catriona Mccallum |
| Date Deposited: | 07 Apr 2006 |
| Last modified: | 12 Mar 2012 10:35 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/728 |
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