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The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by University of Strathclyde researchers, including by researchers from the Department of Computer & Information Sciences involved in mathematically structured programming, similarity and metric search, computer security, software systems, combinatronics and digital health.

The Department also includes the iSchool Research Group, which performs leading research into socio-technical phenomena and topics such as information retrieval and information seeking behaviour.

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A passive tube-type sampler for the determination of formaldehyde vapours in museum enclosures

Gibson, L.T. and Brokerhof, A.W. (2001) A passive tube-type sampler for the determination of formaldehyde vapours in museum enclosures. Studies in Conservation, 46 (4). pp. 289-303. ISSN 0039-3630

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Abstract

A tube-type passive sampling method has been developed and assessed for the quantification of formaldehyde (methanol) vapours in indoor air. The sampler was designed for use in museums where test sites often include small enclosures with low air movement. The procedure involves collection of formaldehyde vapours in a Palmer diffusion tube containing a paper support impregnated with an acidified solution of 2,4-dinitrophenylhydrazine (2,4-DNPH). After sampling, quantification of the trapped F-DNPH is achieved by high performance liquid chromatography (HPLC) analysis with UV detection at 350mm. To validate the procedure, permeation devices were used to generate formaldehyde-containing atmospheres., 81-2975pph, in a 20dm(3) chamber so that experimentally derived sampling rates could be calculated and compared with the theoretical value. Three 2,4-DHPH solutions were investigated to obtain an efficient and stable trapping solution. Best results were achieved with a 27mg.ml(-2) solution of 2,4-DNPH which contained 4(3.)6ml.min(-1). The passive sampling method was repeatable and reproducible with RSD (relative standard deviation) values below 7% for long-term exposures at low air velocities.